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Article
Publication date: 28 October 2014

Rihan Omar Rihan

This paper aims to report an experimental investigation of the galvanic corrosion that occurs between the base metal and the welds in X52 carbon steel petroleum pipelines when…

Abstract

Purpose

This paper aims to report an experimental investigation of the galvanic corrosion that occurs between the base metal and the welds in X52 carbon steel petroleum pipelines when exposed in carbon dioxide (CO2)-containing saltwater at pH 4 at room temperature. The pipeline was fabricated by electric resistance welding (ERW).

Design/methodology/approach

The experimental setup was a closed glass cell equipped with a silver/silver chloride (Ag/AgCl) reference electrode, two working electrodes (the weld metal and the parent steel specimens) and a gas bubbler. The corrosion potential and polarization resistance of the base metal and the weld were determined using electrochemical testing methods: potentiodynamic polarization scans and linear polarization resistance measurement. The galvanic currents of the base metal when coupled to the weld metal were measured using zero resistance ammetry.

Findings

The weld metal was the anode of the couple for a very short time at the beginning of the experiment and then became the cathode until the end of the experiment. This indicates that electric resistance welded X52 steel pipe is a promising material to be operated in CO2-containing saltwater at pH 4 and 25°C because the weld area is cathodic to the parent metal, the value of the galvanic current is very low (in the order of nanoamps) and the area of the anode (i.e. the parent metal) is significantly larger than that of the cathode (weld metal).

Research limitations/implications

Further experimental research could be performed to investigate the galvanic corrosion behavior between the parent metal and the weld area of X52 carbon steel petroleum pipelines in CO2-containing saltwater at different pH values, temperature and velocity.

Practical implications

Electric resistance welded X52 steel pipe is a promising material for use with CO2-containing saltwater environments at pH 4 and 25°C.

Originality/value

The new information presented in the paper is the galvanic corrosion behavior between the parent metal and the ERW weld metal of X52 carbon steel in CO2-containing solutions. The paper should be useful to researchers working in the field of oil industry corrosion.

Details

Anti-Corrosion Methods and Materials, vol. 61 no. 6
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 6 September 2013

Reyad Shawabkeh, Rihan Rihan and Nawaf AL‐Baker

The paper aims to report an experimental investigation of the effectiveness of an alkyl amine‐based inhibitor on the corrosion behavior of 1018 carbon steel in sea water. The…

Abstract

Purpose

The paper aims to report an experimental investigation of the effectiveness of an alkyl amine‐based inhibitor on the corrosion behavior of 1018 carbon steel in sea water. The adsorption equilibrium for this corrosion inhibitor on carbon steel was also investigated. The corrosion inhibitor was evaluated based on parameters such as inhibitor concentration, temperature, stirring speed and pH.

Design/methodology/approach

The experimental setup employed an autoclave with a flow circulation system. Weight loss determinations and electrochemical techniques such as polarization resistance and potentiodynamic polarization were used to detect and monitor the performance of the corrosion inhibitor. Surface examination of the steel substrate before and after applying different doses of inhibitor was undertaken using Fourier transform infrared spectroscopy (FT‐IR), scanning electron microscopy (SEM), and energy dispersive spectrometry (EDS).

Findings

Inhibition efficiency was enhanced by adsorption of amine‐containing functional groups on the steel surface. This adsorption capacity was measured and fitted Langmuir and Shawabkeh‐Tutunji isotherms and was found to require a maximum requirement of 1.08 mg of corrosion inhibitor to provide a monolayer of cover on the carbon steel surface. The inhibition efficiency increased with increasing the inhibitor concentration and solution pH. Moreover, increasing the solution temperature and stirring speed had an adverse effect on inhibition efficiency. Polarization data fitted by the Butler‐Volmer Equation showed the values of anodic and cathodic Tafel coefficients were an average of 0.8 and 0.2, respectively. The measured corrosion rates decreased rapidly within the first hour after commencing the experiments, which is related to the formation of a protective oxide film.

Research limitations/implications

More inhibitor concentrations can be studied in order to draw more comprehensive conclusions on the efficiency of the tested inhibitor.

Practical implications

The effect of alkyl amine‐based inhibitor on the corrosion inhibition characteristic of 1018 carbon steel (CS) in sea water was determined at different inhibitor concentrations, temperatures, stirring speeds and pH.

Originality/value

The new information reported in this paper is the effect of alkyl amine‐based inhibitor on the corrosion characteristics of 1018 carbon steel in seawater using an autoclave with a flow circulation system. The paper is valuable to researchers in the area of corrosion inhibitors and oil and gas industry.

Details

Anti-Corrosion Methods and Materials, vol. 60 no. 5
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 10 October 2016

Hongyan Tian, Jianbing Sang, Rihan Ao and Shujun Hou

As a good absorbing material candidate, a functionally graded wave absorber can be tailored to satisfy the impedance match principle by gradually changing material property. The…

Abstract

Purpose

As a good absorbing material candidate, a functionally graded wave absorber can be tailored to satisfy the impedance match principle by gradually changing material property. The paper aims to discuss these issues.

Design/methodology/approach

The electromagnetic wave absorption properties are discussed. An analysis model is proposed to provide an insight into its mechanical characteristics during wave absorption. Considering the energy-converting and thermal deformation properties, the thermoelastic behaviors of an absorber are analyzed by numerical method. The effects of material and geometrical properties are discussed in detail.

Findings

The results demonstrate that absorbing effect of graded composite is enhanced. Good performance of low reflectance and high absorption with gentle thermal stress distribution can be obtained by proper designing of the gradient absorber.

Originality/value

Functionally graded materials exhibit a progressive compositional gradient change along certain dimension of structures, which can be used as absorbing materials for the gradual change of material property tailored to satisfy the principle of impedance match. The design of functionally graded absorbing materials usually should consider not only the electromagnetic performance, but also the mechanical properties simultaneously. Therefore, few investigations have addressed the mechanical characteristics of absorbers. This paper presents some studies on the electromagnetic, especially mechanical behaviors during electromagnetic wave absorption. It is helpful to provide mechanical reference for designing an absorber.

Details

Multidiscipline Modeling in Materials and Structures, vol. 12 no. 3
Type: Research Article
ISSN: 1573-6105

Keywords

Article
Publication date: 30 April 2020

Kishor Purushottam Jadhav, Amita Mahor, Anirban Bhowmick and Anveshkumar N.

Non-orthogonal multiple access (NOMA) is a much hopeful scheme, which is deployed to enhance the spectral efficiency (SE) significantly, and it also enhances the massive access…

Abstract

Purpose

Non-orthogonal multiple access (NOMA) is a much hopeful scheme, which is deployed to enhance the spectral efficiency (SE) significantly, and it also enhances the massive access that has attained substantial concern from industrial and academic domains. However, the deployment of superposition coding (SC) at the receiver side resulted in interference. For reducing this interference, “multi-antenna NOMA” seems to be an emerging solution. Particularly, by using the channel state information at the transmitter, spatial beam forming could be deployed that eliminates the interference in an effective manner.

Design/methodology/approach

This survey analyzes the literature review and diverse techniques regarding the NOMA-based spatial modulation (SM) environment. It reviews a bunch of research papers and states a significant analysis. Initially, the analysis depicts various transmit antenna selection techniques that are contributed in different papers. This survey offers a comprehensive study regarding the chronological review and performance achievements in each contribution. The analytical review also concerns on the amplitude phase modulation (APM) selection schemes adopted in several contributions. Moreover, the objective functions adopted in the reviewed works are also analyzed. Finally, the survey extends with various research issues and its gaps that can be useful for the researchers to promote improved future works on NOMA-based SM.

Findings

This paper contributes to a review related to NOMA-based SM systems. Various techniques and performance measures adopted in each paper are analyzed and described in this survey. More particularly, the selection of transmission antenna and APM are also examined in this review work. Moreover, the defined objective function of each paper is also observed and made a chronological review as well. Finally, the research challenges along with the gaps on NOMA-based SM systems are also elaborated.

Originality/value

This paper presents a brief analysis of NOMA-based SM systems. To the best of the authors’ knowledge, this is the first work that uses NOMA-based SM systems to enhance SE.

Details

International Journal of Pervasive Computing and Communications, vol. 16 no. 2
Type: Research Article
ISSN: 1742-7371

Keywords

Article
Publication date: 6 December 2018

Yuanpeng Cheng, Yu Bai, Zili Li and JianGuo Liu

The purpose of this paper was to investigate the corrosion behavior of X65 steel in the CO2/oil/water environment using mass loss method, potentiodynamic polarization technique…

Abstract

Purpose

The purpose of this paper was to investigate the corrosion behavior of X65 steel in the CO2/oil/water environment using mass loss method, potentiodynamic polarization technique and characterization of the corroded surface techniques.

Design/methodology/approach

The weight loss analysis, electrochemical study and surface investigation were carried out on X65 steel that had been immersed in the CO2/oil/water corrosive medium to understand the corrosion behavior of gathering pipeline steel. The weight loss tests were carried out in a 3L autoclave, and effects of flow velocity, CO2 partial pressure and water cut on the CO2 corrosion rate of X65 steel were studied. Electrochemical studies were carried out in a three-electrode electrochemical cell with the test temperature of 60°C and CO2 partial pressure of 1 atm by recording open circuit potential/time and potentiodynamic polarization characteristics. The surface and cross-sectional morphologies of corrosion product scales were characterized using scanning electron microscopy. The phases of corrosion product scales were investigated using X-ray diffraction.

Findings

The results showed that corrosion rates of X65 steel both increased at first and then decreased with the increase of flow velocity and CO2 partial pressure, and there were critical velocity and critical pressure in the simulated corrosive environment, below the critical value, the corrosion products formed on the steel surface were loose, porous and unstable, higher than the critical value, the corrosion product ?lms were dense, strong adhesion, and had a certain protective effect. Meanwhile, when the flow velocity exceeded the critical value, oil film could be adsorbed on the steel surface more evenly, corrosion reaction active points were reduced and the steel matrix was protected from being corroded and crude oil played a role of inhibitor, thus it influenced the corrosion rate. Above the critical CO2 partial pressure, the solubility of CO2 in crude oil increased, the viscosity of crude oil decreased and its fluidity became better, so that the probability of oil film adsorption increased, these factors led to the corrosion inhibition of X65 steel reinforced. The corrosion characteristics of gathering pipeline steel in the corrosive environment containing CO2 would change due to the presence of crude oil.

Originality/value

The results can be helpful in selecting the suitable corrosion inhibitors and targeted anti-corrosion measures for CO2/oil/water corrosive environment.

Details

Anti-Corrosion Methods and Materials, vol. 66 no. 2
Type: Research Article
ISSN: 0003-5599

Keywords

Abstract

Details

Organizational Behavior Management
Type: Book
ISBN: 978-1-78769-678-5

Article
Publication date: 6 June 2016

X.Q. Liu, Z.L. Liu, J.D. Hu, Z.G. Hou, Q.C. Tian and H.Z. Wang

The purpose of this study is to explore the corrosion behaviors of tube pile steel with the addition of 0.2 per cent Cu and 0.2 per cent Cu-0.2 per cent Cr in half-immersion…

Abstract

Purpose

The purpose of this study is to explore the corrosion behaviors of tube pile steel with the addition of 0.2 per cent Cu and 0.2 per cent Cu-0.2 per cent Cr in half-immersion environment.

Design/methodology/approach

The electrochemical corrosion behaviors of tube pile steel with different alloy-elements addition were identified using the polarization curve method and electrochemical impedance spectroscopy technique. Corrosion product and its morphology were analyzed by X-ray diffraction, optical microscope and scanning electron microscopy.

Findings

Results indicate that the most serious corrosion occurred in the liquid-air interface zone due to the higher oxygen and water concentration. With the addition of Cu and Cu-Cr, pits were getting smaller and denser, transforming the corrosion type from pitting corrosion to uniform corrosion gradually. Rust layer containing Cu/Cr tended to compact and inhibited the anodic process, while the enrichment of Cu/Cr in rust layer decelerated the dissolution of substrate, thus the expanding of pits was suppressed.

Originality/value

This paper studied the corrosion behaviors of liquid-air interface zone of tube pile steel and verified the transformation of corrosion type with adding Cu, Cu/Cr elements.

Details

Anti-Corrosion Methods and Materials, vol. 63 no. 4
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 6 July 2020

Longfei Song, Zhiyong Liu, Lin Lu, Xiaogang Li, BaoZhuang Sun and Huanlin Cheng

This paper aims to analyze a failure case of a P110 tube in a CO2 flooding well.

Abstract

Purpose

This paper aims to analyze a failure case of a P110 tube in a CO2 flooding well.

Design/methodology/approach

The chemical composition, microstructure and mechanical properties of the failed P110 tubing steel were tested, and met the API Spec 5CT standard. The fractures were investigated by scanning electron microscopy and energy dispersive spectroscopy.

Findings

Fracture was induced by stress corrosion cracking (SCC) and that the stress concentration caused by the mechanical damage played an important role in the failure. The failure case is a SCC failure affected by mechanical damage and galvanic corrosion.

Originality/value

The effect of the infiltration of groundwater was studied in the failure case. The stress concentration caused by the mechanical damage played an important role in the failure.

Details

Anti-Corrosion Methods and Materials, vol. 67 no. 5
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 25 February 2022

Jie Kou, Dongxu Ma and Le Yang

Oil-water two-phase flow is the most prevalent medium in oil field gathering pipelines, and the corrosion of pipelines is often highly localized. Therefore, the purpose of this…

Abstract

Purpose

Oil-water two-phase flow is the most prevalent medium in oil field gathering pipelines, and the corrosion of pipelines is often highly localized. Therefore, the purpose of this paper is to investigate the corrosion behavior of 20# pipeline steel in the oil-water stratified liquids, vary the water content of the upper emulsion and study the difference of the corrosion process.

Design/methodology/approach

Combine the wire beam electrodes (WBE) technique and the corrosion weight loss method to investigate the corrosion behavior of 20# steel in produced water simulation fluid and oil-water stratified liquids, and a corrosion mechanism model was established for analysis and explanation.

Findings

The results of mass loss experiments showed that the average corrosion rate increased with the increase in the water content of the upper emulsion. The corrosion current distribution maps indicated that the most serious corrosion occurred in the produced water simulation liquid, and the corrosion process showed the law of waterline corrosion. In addition, it was also found that the corrosion of the WBE in the stratified liquids had obvious non-uniformities. The electrode wires at the oil-water interface suffered from severe corrosion, caused by the dissolution of crude oil acids in water and the uneven distribution of oxygen in the corrosive medium.

Originality/value

The WBE technique provides a deep insight into the corrosion phenomena at the oil-water interface, which is helpful for characterization of the non-uniformity of corrosion parameters and evaluating the risks of multiphase corrosive media.

Details

Anti-Corrosion Methods and Materials, vol. 69 no. 3
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 5 June 2017

Yuanpeng Cheng, Zili Li, Yalei Zhao, Yazhou Xu, Qianqian Liu and Yu Bai

The purpose of this paper was to investigate the corrosion behaviour of API X65 pipeline steel in the simulated CO2/oil/water emulsion using weight loss technique, potentiodynamic…

292

Abstract

Purpose

The purpose of this paper was to investigate the corrosion behaviour of API X65 pipeline steel in the simulated CO2/oil/water emulsion using weight loss technique, potentiodynamic polarization technique and characterization of the corroded surface techniques.

Design/methodology/approach

The weight loss analysis, electrochemical study and surface investigation were carried out on API X65 pipeline steel that had been immersed in the CO2/oil/water corrosive medium to understand the corrosion behaviour of gathering pipeline steel. The weight loss tests were carried out in a 3L autoclave, and effects of temperature, CO2 partial pressure, water cut and flow velocity on the CO2 corrosion rate of API X65 pipeline steel were studied. Electrochemical studies were carried out in a three-electrode electrochemical cell with the test temperature was 60°C, and the CO2 partial pressure was 1 atm by recording open circuit potential/time and potentiodynamic polarization characteristics. The surface and cross-sectional morphologies of corrosion product scales were characterized using scanning electron microscopy. The phases of corrosion product scales were investigated using X-ray diffraction.

Findings

The results showed that water cut was the main controlling factor of API X65 steel corrosion under the conditions of CO2/oil/water multiphase flow, and it had significant impact on corrosion morphology. In the case of higher water cut or pure water phase, general corrosion occurred on the steel surface. While water cut was below 70 per cent, corrosion morphology transformed into localized corrosion, crude oil decreased corrosion rate significantly and played a role of inhibitor. Crude oil hindered the corrosion scales from being dissolved by corrosive medium and changed dimension and accumulation pattern of the crystal grain, thickness and structure of the corrosion scales; thus, it influenced the corrosion rate. The primary corrosion product of API X65 steel was ferrous carbonate, which could act as a protective film at low water cut so that the corrosion rate can be reduced.

Originality/value

The results can be helpful in selecting the suitable corrosion inhibitors and targeted anti-corrosion measures for CO2/oil/water corrosive environment.

Details

Anti-Corrosion Methods and Materials, vol. 64 no. 4
Type: Research Article
ISSN: 0003-5599

Keywords

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